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💧Hydrogen bond vs Dipole-dipole🧲

Both are intermolecular attractions between polar molecules, but hydrogen bonding is a stronger special case. It explains water's unusual properties.

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💧Hydrogen bond
  • Strongest intermolecular attraction (non-ionic)
  • Requires H bonded to N, O or F
  • Raises boiling points dramatically
  • Explains water's high boiling point and ice density
  • Examples: water, DNA base pairing, NH3
🧲Dipole-dipole
  • Weaker than hydrogen bonding
  • Occurs between any polar molecules
  • Aligns partial positive and negative ends
  • Moderately raises boiling points
  • Examples: HCl, acetone, SO2

Verdict

Hydrogen bonding is just a powerful subtype of dipole-dipole interaction restricted to N-H, O-H and F-H. Both pull polar molecules together, but hydrogen bonds win on strength.

Frequently asked

Is a hydrogen bond a real chemical bond?+

No. It is a strong intermolecular force, weaker than covalent or ionic bonds within molecules.

Why does water float as ice?+

Hydrogen bonds lock water molecules into an open hexagonal lattice that is less dense than liquid water.

Which is stronger?+

Hydrogen bonds are stronger because of the highly concentrated charge on small N, O and F atoms.

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